The decomposition of allyloxychlorocarbene in hydrocarbon solvents leads via homolysis to allyl and COCl radicals, which recombine to 3-butenoyl chloride or (after scission of (*)COCl to CO and (*)Cl) to allyl chloride. Labeling experiments show that both products are formed in part with allylic rearrangement.
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| http://dx.doi.org/10.1021/ol050668o | DOI Listing |
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