A catalytic enantioselective hetero Diels-Alder approach to the C20-C32 segment of the phorboxazoles.

J Org Chem

Department of Chemistry, University of Wisconsin, 1101 University Avenue, Madison, Wisconsin 53706-1396, USA.

Published: April 2005

[reaction: see text] An efficient synthesis of the C20-C32 segment of the phorboxazoles has been achieved using an enantioselective hetero Diels-Alder reaction catalyzed by Jacobsen's Cr(III) amino indanol Schiff base catalyst.

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http://dx.doi.org/10.1021/jo050034vDOI Listing

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