The adsorption of arsenic(V) was investigated using macroporous resin beads containing magnetite crystals. Arsenic(V) was favorably adsorbed at pH 2-9, where the distribution coefficients were larger than 10(3). The maximum capacity was 0.050 mmol/g. Metal cations including Ca(II), Mn(II), Co(II), Ni(II), Cu(II), Zn(II) and La(III) did not give serious interference at 10(-4) M level. Diluted arsenic(V) was collected with a packed column, and the retained arsenic(V) was quantitatively eluted out with 1 M NaOH.

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http://dx.doi.org/10.2116/analsci.21.433DOI Listing

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