Photoinduced one-electron reduction of MV2+ in titania nanosheets using porphyrin in mesoporous silica thin films.

Langmuir

Department of Crystalline Materials Science, Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa-ku, 464-8603, Japan.

Published: March 2005

Composite films of a meso-(tetramethylpyridinium)porphyrin (TMPyP) hybrid incorporated in mesoporous silica (MPS) and cast on a methyl viologen (MV2+)/titania nanosheet hybrid were synthesized and a light-induced charge separation between the two could be observed. These composite thin films were able to initiate a one-electron reduction of the MV2+ ions accompanied by the simultaneous decomposition of the TMPyP organic dye within the mesoporous silica channels.

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http://dx.doi.org/10.1021/la047385+DOI Listing

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