Spontaneous resolution in a halogen bonded supramolecular architecture.

Chem Commun (Camb)

NFMLab-Department of Chemistry, Materials and Chemical Engineering G. Natta, Polytechnic of Milan, Via L. Mancinelli 7, 20131, Milan, Italy.

Published: March 2005

The halogen bonding driven self-assembly of 1,8-diiodoperfluorooctane and N,N,N',N'-tetramethyl-p-phenylenediamine induces the formation of a chiral and enantiopure co-crystal wherein the fluorinated chains adopt an unusual gauche arrangement.

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http://dx.doi.org/10.1039/b417771aDOI Listing

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