In preferential CO oxidation in H2-rich gas, K-Pt/Al2O3(K/Pt = 10) was very effective in decreasing CO concentration below 10 ppm in the 375-410 K range, and the turnover frequency of the K-Pt/Al2O3 was 20 times as high as that of Pt/Al2O3 at 353 K; furthermore, the activity of CO oxidation was promoted drastically by the presence of H2.
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http://dx.doi.org/10.1039/b416565a | DOI Listing |
Chem Mater
January 2025
Department of Chemistry and Nanoscience Center, University of Copenhagen, 2100 Copenhagen Ø, Denmark.
Bismuth ferrites, specifically perovskite-type BiFeO and mullite-type BiFeO, hold significant technological promise as catalysts, photovoltaics, and room-temperature multiferroics. However, challenges arise due to their frequent cocrystallization, particularly in the nanoregime, hindering the production of phase-pure materials. This study unveils a controlled sol-gel crystallization approach, elucidating the phase formation complexities in the bismuth ferrite oxide system by coupling thermochemical analysis and total scattering with pair distribution function analysis.
View Article and Find Full Text PDFJ Hazard Mater
January 2025
School of Environmental Science and Engineering, Southwest Jiaotong University, Sichuan, Chengdu 611756, China. Electronic address:
The ultraviolet-activated peroxymosnofulate (UV/PMS) system, an effective advanced oxidation process for removing dissolved organic matter (DOM) from wastewater, is limited by high chloride ion (Cl) concentrations in landfill leachate. This study used Fourier transform ion cyclotron resonance mass spectrometry to explore the transformation of DOM in the UV/PMS system with a high Cl concentration. The results revealed that elevated Cl levels generate reactive chlorine species, including chlorine radicals, dichlorine radicals, and hypochlorous acid/hypochlorite, reducing the total organic carbon (TOC) removal efficiency of Suwannee River natural organic matter (SRNOM) from 78.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Department of Materials Engineering, Ben-Gurion University of the Negev, Beer-Sheva 8410501, Israel.
Cuprous oxide (CuO) thin films were chemically deposited from a solution onto GaAs(100) and (111) substrates using a simple three-component solution at near-ambient temperatures (10-60 °C). Interestingly, a similar deposition onto various other substrates including Si(100), Si(111), glass, fluorine-doped tin oxide, InP, and quartz resulted in no film formation. Films deposited on both GaAs(100) and (111) were found alongside substantial etching of the substrates.
View Article and Find Full Text PDFChemMedChem
January 2025
Kobe Pharmaceutical University: Kobe Yakka Daigaku, Laboratory of Microbial Chemistry, 4-19-1 Motoyamakita, Higashinada, 6588558, Kobe, JAPAN.
The antiausterity strategy in anticancer drug discovery has attracted much attention as a way to exterminate cancer cells under nutrient deprived conditions which are commonly found in solid tumors. These tumors under low nutrient stress are known to be malignant and often resist conventional drug therapy. As a potential drug candidate, we focused on the meroterpenoid natural product callistrilone O which has demonstrated extremely potent antiausterity properties toward PANC-1 pancreatic carcinoma in vitro.
View Article and Find Full Text PDFSmall Methods
January 2025
State Key Laboratory of Green Pesticide, Key Laboratory of Green Pesticide & Agricultural Bioengineering, Ministry of Education, State-Local Joint Laboratory for Comprehensive Utilization of Biomass, Center for R&D of Fine Chemicals, Guizhou University, Guiyang, Guizhou, 550025, China.
Photocatalytic transfer hydrogenation of biomass-derived aldehydes to alcohols often results in unwanted coupling co-products. Herein, an ultraselective hydrogen transfer system enabled by in situ oxidative C─C bond cleavage over a Janus single-atom palladium on titanium dioxide (0.5Pd/TiO) photocatalyst is presented.
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