Silyl methallylsulfinates: efficient and powerful agents for the chemoselective silylation of alcohols, polyols, phenols and carboxylic acids.

Chem Commun (Camb)

Laboratoire de Glycochimie et de Synthèse Asymétrique, Ecole Polytechnique Fédérale de Lausanne, (EPFL), BCH, CH-1015, Lausanne, Suisse.

Published: March 2005

Alcohols, phenols and carboxylic acids are silylated with very good yields in the presence of silyl methallylsulfinates under non-basic conditions and with the formation of volatile co-products.

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Source
http://dx.doi.org/10.1039/b417894gDOI Listing

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