A new cyclization and C-H activation/Stille cross-coupling reaction on a nonactivated aromatic has been discovered. The reaction is regioselective and controlled by the stannylated reagent. Labeling experiments have been performed that provide evidence for a complete transfer of the deuterium through the coordination sphere of palladium. [reaction: see text]
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http://dx.doi.org/10.1021/ol047537s | DOI Listing |
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