Linear and weakly nonlinear thermal convection in a moderately thin spherical shell in the presence of a spherically symmetric gravity subject to a spherically symmetric boundary condition is systematically investigated through fully three-dimensional numerical simulations. The convection problem is self-adjoint and the linear convective stability is characterized by l, the degree of a spherical harmonics Yml (theta,phi). While the radial structure of the linear convection is determined by the stability analysis, there exists a (2l + 1)-fold degeneracy in the horizontal structure of the spherical convection. When l = O(10) , i.e., in a moderately thin spherical shell, the removal or partial removal of the degeneracy represents a mathematically difficult, physically not well-understood problem. By starting with carefully chosen initial conditions, we are able to obtain a variety of nonlinear convective flows at exactly the same parameters near the onset of convection, including steady axisymmetric convection, steady azimuthally periodic convection, steady azimuthally nonperiodic convection, equatorially asymmetric convection, and steady convection in the form of a single giant spiral roll covering the whole spherical shell which is stable and robust for a wide range of the Prandtl number.
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http://dx.doi.org/10.1103/PhysRevE.71.016301 | DOI Listing |
Sci Rep
January 2025
School of Chemistry, Institute of Science, Suranaree University of Technology, Nakhon Ratchasima, 30000, Thailand.
In this work, we synthesize a quinoline-based heptamethine cyanine, QuCy7, with sulfonate groups to enhance water solubility. This dye demonstrates exceptional near-infrared absorption beyond 750 nm, accompanied by photothermal properties but low photostability. Encapsulating QyCy7 with polyethylene glycol to form nanopolymer, QuCy7@mPEG NPs, addresses the issue of its photoinstability.
View Article and Find Full Text PDFNeuroimage
January 2025
Dept. of Electrical and Computer Engineering, Worcester Polytechnic Institute, Worcester, MA, USA.
A fast BEM (boundary element method) based approach is developed to solve an EEG/MEG forward problem for a modern high-resolution head model. The method utilizes a charge-based BEM accelerated by the fast multipole method (BEM-FMM) with an adaptive mesh pre-refinement method (called b-refinement) close to the singular dipole source(s). No costly matrix-filling or direct solution steps typical for the standard BEM are required; the method generates on-skin voltages as well as MEG magnetic fields for high-resolution head models within 90 s after initial model assembly using a regular workstation.
View Article and Find Full Text PDFTalanta
January 2025
State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Engineering Research Center of Technical Textiles, Ministry of Education, College of Materials Science and Engineering, College of Science in Donghua University, State Key Laboratory of Polyolefins and Catalysis, Shanghai Key Laboratory of Catalysis Technology for Polyolefins (Shanghai Research Institute of Chemical Industry Co., Ltd., Shanghai), Key Laboratory of High Performance Fibers & Products, PR China. Electronic address:
Here, a green poly(ionic liquid)-regulated one-pot method is developed for the synthesis of Au@Pt core-shell nanospheres (PNSs) under mild reaction conditions in water. It is found that the poly(ionic liquid) poly[1-methyl-3-butyl (3-hydroxy) imidazole] chloride (PIL-Cl) is very vital to guide the construction of Au@Pt PNSs. The as-obtained Au@Pt-1 PNSs have perfect spherical outlines, porous core-shell structures and large specific surface area by which they exhibit excellent peroxidase-like activity in acidic media and can be used to develop a simple and reliable colorimetric sensing platform.
View Article and Find Full Text PDFLangmuir
January 2025
Department of Applied Chemistry, Graduate School of Engineering, University of Hyogo, Shosha, Himeji, Hyogo 671-2201, Japan.
To prepare amphiphilic diblock copolymers (MP), a controlled radical polymerization approach was employed, incorporating hydrophilic poly(2-(methacryloyloxy)ethyl phosphorylcholine) (PMPC) with hydrophobic poly(3-methoxypropyl acrylate) (PMPA). The synthesized diblock copolymers feature a PMPC block with a degree of polymerization (DP) of 100 and a PMPA block with DP (=) values of 171 and 552. The hydrophilic PMPC block exhibits biocompatibility, such as inhibition of platelet and protein adsorption, because of its hydrophilic pendant zwitterionic phosphorylcholine groups that have the same chemical structure as cell membrane surfaces.
View Article and Find Full Text PDFNano Lett
January 2025
Key Laboratory of Physics and Technology for Advanced Batteries, College of Physics, Jilin University, Changchun 130012, China.
Lanthanide-doped fluoride nanocrystals have emerged as promising tools in biomedicine, yet their applications are still limited by their low luminescence efficiency. Herein, we developed highly efficient lithium-based core-shell-shell (CSS) nanoprobes (NPs) featuring a rhombic active domain and a spherical inert protective shell. By introducing Yb as an energy transfer bridge and optimizing the CSS design, a remarkable 1643-fold enhancement in visible emission and a 33-fold increase in NIR emission are achieved compared to original nanoparticles.
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