Motivated by recently discovered unusual properties of bulk nematic elastomers, we study a phase diagram of liquid-crystalline polymerized phantom membranes, focusing on in-plane nematic order. We predict that such membranes should generically exhibit five phases, distinguished by their conformational and in-plane orientational properties: namely, isotropic-crumpled, nematic-crumpled, isotropic-flat, nematic-flat, and nematic-tubule phases. In the nematic-tubule phase, the membrane is extended along the direction of spontaneous nematic order and is crumpled in the other. The associated spontaneous symmetries breaking guarantees that the nematic tubule is characterized by a conformational-orientational soft (Goldstone) mode and the concomitant vanishing of the in-plane shear modulus. We show that long-range orientational order of the nematic tubule is maintained even in the presence of harmonic thermal fluctuations. However, it is likely that tubule's elastic properties are qualitatively modified by these fluctuations, which can be studied using a nonlinear elastic theory for the nematic tubule phase that we derive at the end of this paper.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1103/PhysRevE.71.011802 | DOI Listing |
Nanoscale Adv
June 2022
Institute for Micromanufacturing, Louisiana Tech University Ruston LA 71272 USA
A nanoarchitectural approach to the design of functional nanomaterials based on natural aluminosilicate nanotubes and their catalysis, and practical applications are described in this paper. We focused on the buildup of hybrid core-shell systems with metallic or organic molecules encased in aluminosilicate walls, and nanotube templates for structured silica and zeolite preparation. The basis for such an architectural design is a unique AlO/SiO dual chemistry of 50 nm diameter halloysite tubes.
View Article and Find Full Text PDFSoft Matter
September 2021
Department of Physics, Indian Institute of Technology Bombay, Powai-400076, Mumbai, India.
Chiral, rod-like molecules can self-assemble into cylindrical membrane tubules and helical ribbons. They have been successfully modeled using the theory of chiral nematics. Models have also predicted the role of chiral lipids in forming nanometer-sized membrane buds in the cell.
View Article and Find Full Text PDFLangmuir
January 2015
Nanosystem Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba Central 5, 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan.
The dispersibility and liquid crystal formation of a self-assembled lipid nanotube (LNT) was investigated in a variety of aqueous solutions. As the lipid component, we chose a bipolar lipid with glucose and tetraglycine headgroups, which self-assembled into an LNT with a small outer diameter of 16 to 17 nm and a high axial ratio of more than 310. The LNT gave a stable colloidal dispersion in its dilute solutions and showed spontaneous liquid crystal (LC) alignment at relatively low concentrations and in a pH region including neutral pH.
View Article and Find Full Text PDFACS Appl Mater Interfaces
October 2011
International Iberian Nanotechnology Laboratory (INL), Av. Mestre José Veiga, 4715-330 Braga, Portugal.
The self-organizing structures formed by a water-soluble perylene diimide dye (PDI) have been studied by several experimental techniques as potential templates for the preparation of hybrid nanomaterials. The dye forms chromonic-nematic and hexagonal liquid crystals in water. The aggregates in liquid crystals consist of one-molecule-wide stacks.
View Article and Find Full Text PDFPhys Rev E Stat Nonlin Soft Matter Phys
September 2008
Department of Physics and Astronomy, University of Pennsylvania, Philadelphia, Pennsylvania 19104, USA.
We study anomalous elasticity in the tubule phases of nematic and smectic elastomer membranes, which are flat in one direction and crumpled in another. These phases share the same macroscopic symmetry properties including spontaneously broken in-plane isotropy and hence belong to the same universality class. Below an upper critical value D_{c}=3 of the membranes' intrinsic dimension D , thermal fluctuations renormalize the elasticity with respect to elastic displacements along the tubule axis so that elastic moduli for compression along the tubule axis and for bending the tubule axis become length-scale dependent.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!