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Selective organocatalytic oxygenation of hydrocarbons by dioxygen using anthraquinones and N-hydroxyphthalimide. | LitMetric
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Selective organocatalytic oxygenation of hydrocarbons by dioxygen using anthraquinones and N-hydroxyphthalimide.

Guanyu Yang Qiaohong Zhang Hong Miao Xinli Tong Jie Xu

Org Lett

State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Graduate School of the Chinese Academy of Sciences, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian, 116023, PR China.

Published: January 2005

[Reaction: see text] Purely organic and catalytic systems of anthraquinones and N-hydroxyphthalimide efficiently promote oxygenation of hydrocarbons with dioxygen under mild conditions, e.g., fluorene can be converted completely to fluorenone with 85% yield at 80 degrees C.

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 Source
http://dx.doi.org/10.1021/ol047749pDOI Listing

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