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Bicyclometalation of aromatic substrates containing imine anchoring groups is achieved with a dimethyliron complex at -70 degrees C; azadiene systems undergo a regiospecific activation of 1,4-CH/N interchanged C-H bonds which may be aromatic or vinylic.
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| http://dx.doi.org/10.1039/b413409e | DOI Listing |
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Meridional bicyclometalation with iron: a novel way of forming dianionic [C,N,C]-ligands.
Chem Commun (Camb)
January 2005
Eduard-Zintl-Institut für Anorganische und Physikalische Chemie, Technische Universität Darmstadt, Petersenstrasse 18, D-64287, Darmstadt, Germany.
Bicyclometalation of aromatic substrates containing imine anchoring groups is achieved with a dimethyliron complex at -70 degrees C; azadiene systems undergo a regiospecific activation of 1,4-CH/N interchanged C-H bonds which may be aromatic or vinylic.
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