Individual fundamental mode dependence of H2O vibrational excitation in the 6-8 eV resonance region by electron impact.

Resonance phenomena in the bending (010), symmetric (100), and asymmetric (001) stretching vibrational modes in water (H(2)O) molecules have been investigated by measuring differential cross sections (DCSs) at fixed energy losses of 0.43, 0.46, 0.49, and 0.51 eV while sweeping the impact energies from 1.6 to 10 eV, at angles 60 degrees and 90 degrees, using a crossed-beam method. No resonancelike enhanced features have been observed in the study of the (010) mode. In the DCSs for the combined (100+001) mode, a single broad hump was observed at each angle, whose position shifts towards the higher energy side with increasing scattering angle, a feature typical of the interference profiles previously observed in a study of the (301) vibrational mode. DCSs for the (001) mode exhibited a rather isotropic angular distribution with no evidence of resonances. However, enhancement of DCSs were indeed observed for the (100) mode, at the energy loss of 0.46 eV, which is attributable to the A(1) symmetry resonance that was studied by Seng and Linder [J. Phys. B 9, 2539 (1976)], with a typical s-wave characteristic angular distribution. Theoretical analysis based on the continuum multiple-scattering approach has been carried out to provide rationale to the experimental results.