AI Article Synopsis
- The study analyzed the thermal decomposition products of (+/-)-linalyl beta-D-glucoside using GC and GC/MS techniques.
- Mild pyrolysis of the glucoside under vacuum produced 2,6-dimethyl-2,6-octadienes, which were identified and characterized through mass spectrometry (MS) and nuclear magnetic resonance (NMR) spectroscopy.
- A stable isotope labeling experiment provided direct evidence for a new reaction mechanism involving proton transfer during the decomposition process.
Article Abstract
Thermally decomposed products of (+/-)-linalyl beta-D-glucoside were analyzed by GC and GC/MS. 2,6-dimethyl-2,6-octadienes produced by mild pyrolysis of linalyl beta-D-glucopyranoside under a vacuum were detected and characterized by MS and NMR spectroscopy. This suggests that 2,6-dimethyl-2,6-octadienes are produced during thermal decomposition of the glucoside via proton transfer from the anomeric position to C-6 in the aglycon moiety. A stable isotope labeling experiment directly indicated the new reaction mechanism.
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| http://dx.doi.org/10.1271/bbb.68.2656 | DOI Listing |
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