The first transition-metal (Rh(I), Mo(VI), Ni(II)) complexes of S[double bond, length as m-dash]P(NHBu(t))(3) have been synthesized via metathetical reactions of mono-lithiated and [Rh(CO)(2)Cl](2), (Bu(t)N)(2)MoCl(2)(dme) and NiBr(2)(dme). Surprisingly in the molecular structure of the Ni(II)-complex both hard-soft (N,S) and hard-hard (N,N[prime or minute]) chelation modes of are realized.
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| http://dx.doi.org/10.1039/b413555e | DOI Listing |
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