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catena-Poly[[heptakis(dimethylformamide-kappaO)di-mu4-oxo-tetra-mu3-oxo-hexadeca-mu2-oxo-tetraoxolanthanum(III)octamolybdenum(IV)]-mu-sodium(I)]. | LitMetric
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catena-Poly[[heptakis(dimethylformamide-kappaO)di-mu4-oxo-tetra-mu3-oxo-hexadeca-mu2-oxo-tetraoxolanthanum(III)octamolybdenum(IV)]-mu-sodium(I)].

Shu-Mei Chen Can-Zhong Lu Ya-Qin Yu Quan-Zheng Zhang Xiang He

Acta Crystallogr C

The State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, National Center for Nanoscience and Nanotechnology, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, People's Republic of China.

Published: November 2004

The title compound, [NaLaMo(8)O(26)(C(3)H(7)NO)(7)](n), contains infinite chains of [Mo(8)O(26)](4-) units supporting dimethylformamide-coordinated La(III) cations and linked by Na(+) cations. The lanthanum center adopts a nine-coordinate geometry and the Na atom is sandwiched between two beta-[Mo(8)O(26)](4-) units.

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http://dx.doi.org/10.1107/S010827010402147XDOI Listing

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