The highly active absorbent with oxidization based on fly ash, lime and additive was prepared. Experiments of simultaneous desulfurization and denitrification were carried out using fixture bed and duct injection. The influencial factors for the absorptive capacity of the absorbent were studied. The absorptive capacities of 120.7 mg for SO2 and 43.7 mg for NOx were achieved at a Ca/(S + N) molar ratio 1.2, respectively, corresponding removal efficiencies of 87% and 76%, while spent absorbent appeared in the form of dry powder. The optimal temperature and humidity of flue gas treated with this process were shown to be approximately 50 degrees C, and 5% respectively. The mechanism of removal for SO2 and NOx was investigated. In comparison with traditional dry FGD, this process appears to have lower cost, less complicated configuration and simpler disposal of used absorbent. The valuable references can be provided for industrial application by this process. The foreground of application will be vast in China and in the world.
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J Environ Manage
December 2024
Key Laboratory of Environmental Pollution Control Technology Research of Zhejiang Province, Eco-environmental Science Research & Design Institute of Zhejiang Province, Hangzhou, 310007, China.
This study focuses on the coupled process of bio-enhanced absorption and biodesulfurization for the toxic gas HS and the greenhouse gas CO. The results show that on the basis of stabilized absorption of HS and CO by alkaline solution (Stage I), the addition of air-lift bioreactor process solution in the absorption column enhanced their absorption (Stage II). Specifically, at constant inlet concentrations of H₂S and CO₂ of 3% (30,000 ppmv) and 30% (300,000 ppmv), respectively, the outlet gases were primarily H₂S, CO₂, and N₂.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
December 2024
School of Materials Science and Engineering, National Institute for Advanced Materials, TKL of Metal and Molecule-Based Material Chemistry, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin, 300350, China.
Metal-organic frameworks (MOFs) have great prospects as adsorbents for industrial gas purification, but often suffer from issues of water stability and competitive water adsorption. Herein, we present a hydrolytically stable MOF that could selectively capture and recover trace SO from flue gas, and exhibits remarkable recyclability in the breakthrough experiments under wet flue-gas conditions, due to its excellent resistance to the corrosion of SO and the water-derived capillary forces. More strikingly, its SO capture efficiency is barely influenced by the increasing humidity, even if the pore filling with water is reached.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
December 2024
State Key Laboratory of Advanced Metallurgy, University of Science and Technology Beijing, Xueyuan Road 30#, Haidian District, Beijing, 100083, China.
Biodegradation
December 2024
Department of Environmental Engineering, Middle East Technical University, 06800, Ankara, Turkey.
This study focused on a new approach for valorization of both ground tire rubber (GTR) and nitrate-containing wastewater via simultaneous devulcanization and denitrification. Initially, sulfur-based autotrophic denitrifiers were successfully enriched from three different seed sludge sources, biological nutrient removal (BNR) sludge, anaerobic digester sludge and BNR sludge of a leather organized industrial zone WWTP. Average nitrate removal efficiencies were 96-98%.
View Article and Find Full Text PDFBioorg Chem
December 2024
State Key Laboratory of Southwestern Chinese Medicine Resources, School of Pharmacy, Chengdu University of Traditional Chinese Medicine, Chengdu 611137, China; Sichuan New Green Pharmaceutical Technology Development Co. Ltd., Chengdu 611930, China. Electronic address:
Psoriasis is an autoimmune inflammation-related disease accompanied by a variety of complications. Reactive oxygen species (ROS) are modulators of inflammation, and their excessive production caused by oxidative/anti-oxidative imbalance has been observed in psoriatic patients. Hypochlorous acid (HOCl) is a ROS produced by myeloperoxidase (MPO) from chloride ions (Cl) and hydrogen peroxide (HO).
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