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miR-195-5p Inhibits Colon Cancer Progression via KRT23 Regulation.

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National Institute of Gastroenterology S. De Bellis, IRCCS Research Hospital, Via Turi 27, 70013 Castellana Grotte, BA, Italy.

Background/objectives: KRT23 was recently discovered as an epithelial-specific intermediate filament protein in the type I keratin family. Many studies have underlined keratin's involvement in several biological processes as well as in the pathogenesis of different diseases. Specifically, KRT23 was reported to affect the structural integrity of epithelial cells and to trigger cellular signaling leading to the onset of cancer.

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Epichlorohydrin is used as an intermediate for the synthesis of polymers and, more particularly, epoxy adhesives. The traditional process involves the cleavage of the carbon-chlorine bond in an alkaline solution. Here, we investigate the breakage of this bond induced by low-energy (<10 eV) electrons.

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Benzylic C-H Oxidation: Recent Advances and Applications in Heterocyclic Synthesis.

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December 2024

School of Chemistry and Physics, University of KwaZulu-Natal, Scottsville, Pietermaritzburg 3209, South Africa.

Benzylic C-H oxidation to form carbonyl compounds, such as ketones, is a fundamental transformation in organic synthesis as it allows for the preparation of versatile intermediates. In this review, we highlight the synthesis of aromatic ketones via catalytic, electrochemical, and photochemical oxidation of alkylarenes using different catalysts and oxidants in the past 5 years. Additionally, we also discuss the synthesis of heterocyclic molecules using benzylic C-H oxidation as a key step.

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Construction of Heterostructured NiS@V-NiFe(III) LDH for Enhanced OER Performance.

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Liuzhou Key Laboratory of New Energy Vehicle Power Lithium Battery, Guangxi Engineering Research Center for Characteristic Metallic Powder Materials, School of Electronic Engineering, Guangxi University of Science and Technology, Liuzhou 545000, China.

The oxygen evolution reaction (OER), which involves a four-electron transfer and slow kinetics, requires an efficient catalyst to overcome the high energy barrier for high-performance water electrolysis. In this paper, a novel NiS@V-NiFe(III) LDH/NF catalyst was prepared via a facile two-step hydrothermal method. The constructed heterostructure of NiS@V-NiFe(III) LDH increases the specific surface area and regulates the electronic structure.

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C-S lyase is a crucial enzyme responsible for the formation of sulfur-containing flavor compounds in . We investigated the involvement of C-S lyase in the synthesis of ergothioneine (EGT) in , a high-producing edible mushroom. Through experimental and computational approaches, we identified 2, a C-S lyase, as a key enzyme involved in EGT synthesis in .

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