Structures of new secofriedelane and friedelane acids from Calophyllum inophyllum of French Polynesia.

Magn Reson Chem

Laboratoire de Chimie Analytique Appliquée, Université de la Polynésie Française, BP 6570, 98702 Faaa, Tahiti, French Polynesia.

Published: January 2005

Three new friedelane-type triterpenoids, 3,4-secofriedelan-3,28-dioic acid (1), 27-hydroxyacetate canophyllic acid (2) and 3-oxo-27-hydroxyacetate friedelan-28-oic acid (3), were isolated from the leaves of Calophyllum inophyllum (Clusiaceae) grown in French Polynesia. Their structures were established by the concerted application of 2D NMR techniques including gs-COSY, gs-HMQC and gs-HMBC.

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http://dx.doi.org/10.1002/mrc.1476DOI Listing

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