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New Pb-Pb bonds: syntheses and molecular structures of hexabiphenyldiplumbane and tri(trisbiphenylplumbyl)plumbate. | LitMetric
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New Pb-Pb bonds: syntheses and molecular structures of hexabiphenyldiplumbane and tri(trisbiphenylplumbyl)plumbate.

Yuzhong Wang Brandon Quillian Pingrong Wei Xiao-Juan Yang Gregory H Robinson

Chem Commun (Camb)

Department of Chemistry, The University of Georgia, Athens, Georgia, USA 30602-2556, USA.

Published: October 2004

Reaction of lead(II) chloride with biphenylmagnesium bromide yields Bp(3)Pb-PbBp(3) and [(THF)(3)Mg(mu-Cl)(3)Mg(THF)(3)][Pb(PbBp(3))(3)](Bp = biphenyl), which, upon single crystal X-ray crystallographic analysis, reveals an interesting variation of Pb-Pb bond distances.

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 Source
http://dx.doi.org/10.1039/b408860nDOI Listing

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