A series of N-alkyl-N-methylpyrrolidinium halide salts have been synthesized and investigated as potentially useful and tunable detergents for a variety of applications.
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http://dx.doi.org/10.1039/b410301g | DOI Listing |
Biomedicines
January 2025
Perron Institute for Neurological and Translational Science, Nedlands 6009, Australia.
Background/objectives: The role of α-synuclein (α-syn) pathology in Parkinson's disease (PD) is well established; however, effective therapies remain elusive. Two mechanisms central to PD neurodegeneration are the intracellular aggregation of misfolded α-syn and the uptake of α-syn aggregates into neurons. Cationic arginine-rich peptides (CARPs) are an emerging class of molecule with multiple neuroprotective mechanisms of action, including protein stabilisation.
View Article and Find Full Text PDFFront Plant Sci
January 2025
CSIRO, Glen Osmond, Adelaide, SA, Australia.
Improving crop salinity management requires enhanced understanding of salinity responses of leaf and fine-root traits governing resource acquisition, ideally in relation to ion accumulation at intra- or inter-specific levels. We hypothesized that these responses are coupled towards integrated resource conservation for plants under prolonged salt treatment. We tested the hypothesis with a glasshouse experiment on saplings of six contrasting hybrids, subjected to either control or salt treatment (reverse osmosis water versus 3.
View Article and Find Full Text PDFChemistry
January 2025
Justus-Liebig Universität, Institut für Organische Chemie, Heinrich-Buff-Ring 17, 35392, Giessen, GERMANY.
Aryl diazenes, particularly azobenzenes (AB), represent a versatile class of compounds with significant historical and practical relevance, ranging from dyes to molecular machines, solar thermal and electrochemical storage. Their oxygen-substituted counterparts, azoxybenzenes (AOB), share structural similarities but have been less explored, especially in energy storage applications. This study investigates the redox properties of AOB, comparing them to AB, and evaluates their potential as redox-active materials for energy storage systems.
View Article and Find Full Text PDFCryst Growth Des
January 2025
Department of Chemical Sciences, Bernal Institute, University of Limerick, Limerick V94 T9PX, Republic of Ireland.
Solid-state synthesis is an approach to organic synthesis that is desirable because it can offer minimal or no solvent waste, high yields, and relatively low energy footprints. Herein, we report the solid-state synthesis of a novel Schiff base, 4-{()-[(4-methylpyridin-3-yl)imino]methyl}benzoic acid (), synthesized through the reaction of an amine and an aldehyde. was prepared via solvent-drop (water) grinding (SDG) on a multigram scale with 97% yield and was characterized using FTIR, H NMR, and SCXRD.
View Article and Find Full Text PDFACS Omega
January 2025
Department of Mechanical Engineering and Engineering Science, University of North Carolina at Charlotte, Charlotte, North Carolina 28223, United States.
Electrides are ionic crystals, with electrons acting as anions occupying well-defined lattice sites. These exotic materials have attracted considerable attention in recent years for potential applications in catalysis, rechargeable batteries, and display technology. Among this class of materials, electride semiconductors can further expand the horizon of potential applications due to the presence of a band gap.
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