Unconventional density dependence of the stochastic dynamics in an organic liquid.

Phys Rev E Stat Nonlin Soft Matter Phys

Instituto de Estructura de la Materia, C.S.I.C., Serrano 123, E-28006 Madrid, Spain.

Published: August 2004

The density dependence of the diffusive rotational and center-of-mass dynamics of 2-methyl-pyridine is investigated by means of the concurrent use of quasielastic neutron scattering and molecular dynamics simulations. The dependence of both translation and rotational diffusion coefficients shows a distinctive change of slope with increasing density taking place about rho=0.975 g/cm3. Such a change in the dynamics can be related to observations made in other liquids composed of oblate-spheroidal particles.

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http://dx.doi.org/10.1103/PhysRevE.70.021501DOI Listing

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