Entropy production and thermodynamics of nonequilibrium stationary states: a point of view.

Chaos

Rutgers Hill Center, E. N. S. Paris, I.N.F.N. Roma1, 00185 Rome, Italy.

Published: September 2004

Entropy might be a not well defined concept if the system can undergo transformations involving stationary nonequilibria. It might be analogous to the heat content (once called "caloric") in transformations that are not isochoric (i.e., which involve mechanical work): it could be just a quantity that can be transferred or created, like heat in equilibrium. The text first reviews the philosophy behind a recently proposed definition of entropy production in nonequilibrium stationary systems. A detailed technical attempt at defining the entropy of a stationary states via their variational properties follows: the unsatisfactory aspects of the results add arguments in favor of the nonexistence of a function of state to be identified with entropy; at the same time new aspects and properties of the phase space contraction emerge.

Download full-text PDF

Source
http://dx.doi.org/10.1063/1.1781911DOI Listing

Publication Analysis

Top Keywords

entropy production
8
nonequilibrium stationary
8
stationary states
8
entropy
5
production thermodynamics
4
thermodynamics nonequilibrium
4
stationary
4
states point
4
point view
4
view entropy
4

Similar Publications

Continuous production of entropy and the corresponding energy dissipation is a defining characteristic of nonequilibrium systems. When a system's full chemical kinetic description is known, its entropy production rate can be computed from the microscopic rate constants. However, such a calculation typically underestimates energy dissipation when the states of the underlying system are mesoscopic, i.

View Article and Find Full Text PDF

Ultrasound-Assisted Enzymatic Extraction of the Active Components from Stem and Bioactivity Comparison with .

Molecules

January 2025

Key Laboratory of Forest Plant Ecology of Ministry of Education, Northeast Forestry University, Hexing Road 26, Harbin 150040, China.

(ASC) contains a variety of bioactive compounds and serves as an important traditional Chinese medicinal resource. However, its prolonged growth cycle and reliance on wild populations limit its practical use. To explore the potential of (ASF) as an alternative, this study focused on optimizing the extraction process and assessing the bioactivity of stem extracts.

View Article and Find Full Text PDF

ConspectusLithium-ion batteries are recognized as an important electrochemical energy storage technology due to their superior volumetric and gravimetric energy densities. Graphite is widely used as the negative electrode, and its adoption enabled much of the modern portable electronics technology landscape. However, developing markets, such as electric vehicles and grid-scale storage, have increased demands, including higher energy content and a diverse materials supply chain.

View Article and Find Full Text PDF

Images are important information carriers in our lives, and images should be secure when transmitted and stored. Image encryption algorithms based on chaos theory emerge in endlessly. Based on previous various chaotic image fast encryption algorithms, this paper proposes a color image sector fast encryption algorithm based on one-dimensional composite sinusoidal chaotic mapping.

View Article and Find Full Text PDF

Nonadditive Entropies and Nonextensive Statistical Mechanics.

Entropy (Basel)

January 2025

Department of Physics, Faculty of Arts and Sciences, Izmir University of Economics, Izmir 35330, Turkey.

The centennial Boltzmann-Gibbs statistical mechanics [...

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!