According to Zhu et al. the resonance energy/electron (REPE) in infinite graphite sheets is equal to 0.17 eV. In the present work the REPE was calculated for parallelogram-shaped graphite sheets (PSGSs). The number of Kekulé structures and contributions of benzene-like and naphthalene-like conjugated circuits were taken into account. Analogously to polyacenes, it was found that REPE = 0.00 eV in PSGSs. The convergence is slow. These results indicate that PSGS is less "aromatic" than its infinite counterpart. Therefore addition reactions are expected to be less difficult to carry out in PSGSs than in infinite or rectangular graphite sheets.
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http://dx.doi.org/10.1021/ci049931a | DOI Listing |
Water Res
December 2024
Zhejiang Key Laboratory of Clean Energy Conversion and Utilization, Science and Education Integration College of Energy and Carbon Neutralization, Zhejiang University of Technology, Hangzhou 310014, China. Electronic address:
This study proposes a switching operating mode that alternates between microbial fuel cell (MFC) and microbial electrolysis cell (MEC) to restore the biofilm activity and organic pollutant degradation capacity in bioelectrochemical systems (BESs) during prolonged operation. After the model switching, the toluene degradation kinetics in BESs equipped with graphite sheet (GS) and polyaniline@carbon nanotubes (PANI@CNTs) bioanodes were elevated by 2.10 and 3.
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January 2025
State Key Laboratory for Modification of Chemical Fibers and Polymer Materials & College of Materials Science and Engineering, Donghua University, Shanghai, 201620, China.
High-performance bulk graphite (HPBG) that simultaneously integrates superior electrical conductivity and excellent strength is in high demand, yet it remains critical and challenging. Herein a novel approach is introduced utilizing MOF-derived nanoporous metal/carbon composites as precursors to circumvent this traditional trade-off. The resulting bulk graphite, composed of densely packed multilayered graphene sheets functionalized with diverse cobalt forms (nanoparticles, single atoms, and clusters), exhibits unprecedented electrical conductivity in all directions (in-plane: 7311 S cm⁻¹, out-of-plane: 5541 S cm⁻¹) and excellent mechanical strength (flexural: 101.
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Center for Membrane Separation and Water Science & Technology, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China.
Heatable super hydrophobic polyurethane (PU) sponges (S-GNS/CNT/PVA@PU) containing three-dimensional (3D) carbon nano-networks (CNNs) coatings made from two-dimensional (2D) expanded graphite nano-sheets (GNS) bridged by one-dimensional (1D) carbon nano-tubes (CNT) were constructed using polyvinyl alcohol (PVA) as binder, in which light and/or electric energy could be rapidly converted into heat to reduce the viscosity of spilled heavy oils, resulting in greatly increased oil. Their heavy oil recovery rate could reach 792 kg/(m·h) under combined light and Joule heating of 1 sun and 5 V. Surface heat dissipating coefficient Ks, heat dissipating index n, and surface heat absorption capacity Cs were studied relating to sizes and shapes of surface heating fields under varied heating modes.
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State Key Laboratory of Heavy Oil Processing, College of Chemical Engineering, China University of Petroleum (East China), Qingdao, 266580, P. R. China.
The production of hydrogen peroxide (HO) through two-electron oxygen reduction reaction (2e ORR) has emerged as a more environmentally friendly alternative to the traditional anthraquinone method. Although oxidized carbon catalysts have intensive developed due to their high selectivity and activity, the yield and conversion rate of HO under high overpotential still limited. The produced HO was rapidly consumed by the increased intensity of HO reduction, which could ascribe to decomposition of peroxide radicals under high voltage in the carbon catalyst.
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Department of Chemistry, Ayatollah Amoli Branch, Islamic Azad University, Amol, Iran.
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