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Remarkable structure deformation in phenothiazine trimer radical cation. | LitMetric

Remarkable structure deformation in phenothiazine trimer radical cation.

Org Lett

Department of Chemistry, Graduate School of Science, Osaka City University, Sugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan.

Published: September 2004

[structure: see text] A trimeric phenothiazine and its radical cation were prepared, and their structures were elucidated. In contrast to a largely twisted structure in the neutral species, the radical cation had a unique structure deformation that allowed charge-transfer-type conjugation from the outer phenothiazine rings to the central phenothiazine radical cation.

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Source
http://dx.doi.org/10.1021/ol048698zDOI Listing

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