Ice nucleation on a model hexagonal surface.

Langmuir

University Chemical Laboratory, Lensfield Road, Cambridge CB2 1EW, UK.

Published: September 2004

The adsorption of water on a model hexagonal surface has been studied using accurate intermolecular potentials. The structure and binding energies of single molecules, clusters, and adlayers are obtained. The limiting case of weak, nondirectional surface-water interactions presented here is compared with other cases involving water-water and water-surface interactions of a similar magnitude (partial templating) and dominating water-surface interactions (perfect templating) from the literature. None of these models is conducive to the nucleation of ice, each for different reasons. We comment on the requirements for a good ice-nucleating surface.

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http://dx.doi.org/10.1021/la048958lDOI Listing

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