Candidate methods for improving the electrochemical oxygen production by a solid-oxide electrolyte with the fluorite-type structure and oxide electrodes with the perofskite structure were analyzed. After consideration of mechanisms of oxygen-producing electrode reactions, physical-chemical properties of oxide materials and diagrams of states of substances used as an electrolyte and electrodes in solid-electrolyte systems, a qualitatively new approach to arraying an electrochemical cell with a solid oxide electrolyte and oxide electrodes was proposed.

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