Donor-acceptor nanoensembles, prepared via electrostatic interactions of single wall carbon nanotubes and porphyrin salts, give rise to photoinduced intra-complex charge separation that lasts tens of microseconds.
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http://dx.doi.org/10.1039/b406933a | DOI Listing |
ACS Appl Mater Interfaces
October 2023
Department of Chemistry, UGC Sponsored-Centre of Advance Studies-II, Guru Nanak Dev University, Amritsar, Punjab 143005, India.
The supramolecular assemblies of the donor-acceptor (D-A) system , having phenanthro[9,10-]imidazole as the donor and terpyridyl group as the acceptor unit, have been developed, which serve as supramolecular host to stabilize Co(II) in its nanoform. The as-prepared supramolecular nanoensemble in DMSO:water (7:3) shows high thermal stability and photostability. Even in the case of solvent mismatch, i.
View Article and Find Full Text PDFChem Asian J
August 2020
Theoretical and Physical Chemistry Institute, National Hellenic Research Foundation, 48 Vassileos Constantinou Avenue, Athens, 11635, Greece.
A facile strategy for the controllable growth of CdS nanoparticles at the periphery of MoS en route the preparation of electron donor-acceptor nanoensembles is developed. Precisely, the carboxylic group of α-lipoic acid, as addend of the modified MoS obtained upon 1,2-dithiolane functionalization, was employed as anchor site for the in situ preparation and immobilization of the CdS nanoparticles in an one-pot two-step process. The newly prepared MoS /CdS hybrid material was characterized by complementary spectroscopic, thermal and microscopy imaging means.
View Article and Find Full Text PDFACS Appl Mater Interfaces
February 2019
Theoretical and Physical Chemistry Institute, National Hellenic Research Foundation , 48 Vassileos Constantinou Avenue , 11635 Athens , Greece.
Transition-metal dichalcogenides (TMDs) attract increased attention for the development of donor-acceptor materials enabling improved light harvesting and optoelectronic applications. The development of novel donor-acceptor nanoensembles consisting of poly(3-thiophene sodium acetate) and ammonium functionalized MoS and WS was accomplished, while photoelectrochemical cells were fabricated and examined. Attractive interactions between the negatively charged carboxylate anion on the polythiophene backbone and the positively charged ammonium moieties on the TMDs enabled in a controlled way and in aqueous dispersions the electrostatic association of two species, evidenced upon titration experiments.
View Article and Find Full Text PDFACS Appl Mater Interfaces
December 2017
Theoretical and Physical Chemistry Institute, National Hellenic Research Foundation , 48 Vassileos Constantinou Avenue, Athens 11635, Greece.
The self-assembly of novel core-shell nanoensembles consisting of regioregular poly(3-hexylthiophene) nanoparticles (P3HT) of 100 nm as core and semiconducting CdTe quantum dots (CdTe) as shell with a thickness of a few tens of nanometers was accomplished by employing a reprecipitation approach. The structure, morphology, and composition of CdTe/P3HT nanoensembles were confirmed by high-resolution scanning transmission microscopy and dynamic light-scattering studies. Intimate interface contact between the CdTe shell and the P3HT core leads to the stabilization of the CdTe/P3HT nanoensemble as probed by the steady-state absorption spectroscopy.
View Article and Find Full Text PDFPhotochem Photobiol Sci
April 2017
Área de Química Orgánica Instituto de Bioingeniería, Universidad Miguel Hernández, Elche, Spain.
The liquid exfoliation of graphite to few layered graphene sheets together with the non-covalent supramolecular functionalization of exfoliated graphene by the synthesized N,N'-di(2-ethylhexyl)-1-(N''''-methylpiperazin-N'''-yl)perylene-3,4,9,10-tetracarboxydiimide (Pip-PDI) is reported. The aromatic Pip-PDI has the ability to non-covalently interact with the exfoliated graphene sheets, stabilizing them and preventing their reassembly. On the other hand, the presence of the piperazine moiety on the bay position of the PDI core makes it an ideal electron donor, nicely coupled with the electron accepting exfoliated graphene, hence, forming a novel donor-acceptor nanoensemble, which was characterized by complementary spectroscopic and microscopy techniques.
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