Reversible folding/unfolding of linear molecular strands into helical channel-like complexes upon proton-modulated binding and release of metal ions.

Chem Commun (Camb)

Institut de Science et d'Ingenierie Supramoleculaires (ISIS), 8 allee Gaspard Monge, BP 70028 67083 Strasbourg cedex, France.

Published: September 2004

The binding of appropriate metal ions to linear ligand strands obtained by hydrazone polycondensations generates channel-like complexes by reversible coiling of the ligand, thus allowing the generation of ion-induced, acid-base neutralisation fueled, molecular nanomechanical contraction/extension motions of large amplitude.

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http://dx.doi.org/10.1039/b407168aDOI Listing

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