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Solvent-Driven Synthesis of DNA-Based Liquid Crystalline Organogels with Extraordinary Stretchability, Self-Healing, and Higher-Order Structural Assembly.
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Department of Chemistry, Korea Advanced Institute of Science and Technology (KAIST), Daejeon, 34141, Republic of Korea.
The fabrication of liquid crystalline (LC) organogel via supramolecular interactions between Deoxyribonucleic acid (DNA) and lyotropic cationic surfactant containing cyanobiphenyl moiety is reported. The fabricated organogel endows dominantly viscous behavior in dimethyl sulfoxide (DMSO) and elastic behavior in n-propanol (n-PrOH), respectively. By judiciously controlling the viscosity, DMSO organogels can be drawn to form a fiber with an elongation of up to 4.
View Article and Find Full Text PDFOf the 1.5 million emergency room visits each year in the United States due to flexor tendon injuries in the hand, over 30-40% result in peritendinous adhesions which can limit range of motion (ROM) and severely impact an individual's quality of life. Adhesions are fibrous scar-like tissues which can form between adjacent tissues in the body in response to injury, inflammation, or during normal healing following surgery.
View Article and Find Full Text PDFInsights into the effects of phenolic acids on rice starch properties via noncovalent interactions.
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College of Food Engineering, Harbin University of Commerce, Harbin, China.
The development of advanced starch-based materials is hindered by limited understanding of structure-dependent phenolic acid (PA) binding mechanisms. This study employed a multi-technique approach (Fourier-transform infrared, x-ray diffraction, rheology, molecular docking) to investigate 16 PAs with varying hydroxylation patterns and methoxy substitutions. Three distinct binding modes were identified: (1) Polyhydroxylated acids (e.
View Article and Find Full Text PDFHost-guest interfacial recognition of alginate-based β-cyclodextrin/dendrobine supra-amphiphiles reinforced the physicochemical stability and sustained-release properties of Pickering emulsions.
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School of Pharmacy, Anhui University of Chinese Medicine, 350 Longzihu Road, Hefei 230012, Anhui Province, China. Electronic address:
Achieving high bioavailability of dendrobine (DDB) necessitates the development of simplified available and efficient delivery systems. Pickering emulsions (PEs) derived from biomass represent a promising option. However, the physicochemical properties of PEs interfacial films were insufficient to prevent DDB leakage, thereby reducing bioavailability.
View Article and Find Full Text PDFStructure and supramolecular organization of silver nitrate modified epoxy or amino terminated liquid oligoethers.
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MIREA - Russian Technological University, Lomonosov Institute of Fine Chemical Technologies, 86, Prospekt Vernadskogo, Moscow 119571, Russia.
The behavior of silver nitrate in non-aqueous liquid oligomeric media-aromatic and aliphatic diglycidyl ethers and aliphatic diamine-has been investigated. By employing UV-visible spectrophotometry and dynamic light scattering, it has been shown that in diglycidyl oligomers, regardless of the nature of the monomeric unit, the formation of silver nanoparticles occurs, and the kinetics of this process has been studied. At the same time, in the medium of aliphatic diamine, the reduction of silver ions is absent, indicating the formation of a complex compound.
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