Polymer adsorption onto random planar surfaces: interplay of polymer and surface correlations.

J Chem Phys

Fakultat fur Physik, Universitat Bielefeld, Universitatsstrasse 25, D-33615 Bielefeld, Germany.

Published: September 2004

We study the adsorption of homogeneous or heterogeneous polymers onto heterogeneous planar surfaces with exponentially decaying site-site correlations, using a variational reference system approach. As a main result, we derive simple equations for the adsorption-desorption transition line. We show that it is preferable to have a small amount of strongly adsorbing sites or monomers rather than a greater amount of weakly adsorbing ones. The results are discussed with respect to their implications for the physics of molecular recognition.

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http://dx.doi.org/10.1063/1.1778137DOI Listing

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