Static and dynamic tensiometries show that a newly prepared water/asphaltenated cyclohexane interface behaves as expected: the mean area occupied per asphaltene molecule is 2 nm2, and variations of interfacial tension and dilatational elastic modulus with time indicate that equilibrium is reached more slowly than that for usual surfactants. The use of the time/temperature superposition principle allows a detailed rheological study of a 2 day old interface of the same type which has reached equilibrium. It is found that the two-dimensional asphaltene network exhibits a glass transition zone, behaves as a gel near its gelation point, and is built by a universal process of aggregation.
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http://dx.doi.org/10.1021/la049017b | DOI Listing |
Sci Adv
November 2022
Department of Materials Science and NanoEngineering, Rice University, Houston, TX 77005, USA.
The refining process of petroleum crude oil generates asphaltenes, which poses complicated problems during the production of cleaner fuels. Following refining, asphaltenes are typically combusted for reuse as fuel or discarded into tailing ponds and landfills, leading to economic and environmental disruption. Here, we show that low-value asphaltenes can be converted into a high-value carbon allotrope, asphaltene-derived flash graphene (AFG), via the flash joule heating (FJH) process.
View Article and Find Full Text PDFUltrason Sonochem
February 2022
School of Engineering, King's College, University of Aberdeen, Aberdeen AB24 3UE, UK.
Asphaltene deposition around the wellbore is a major cause of formation damage, especially in heavy oil reservoirs Ultrasonic stimulation, rather than chemical injection, is thought to be a more cost-effective and environmentally friendly means of removing asphaltene deposition. However, it seems to be unclear how crucial features like reservoir pore geometries and ultrasonic parameters affect this ultrasound treatment. In this work, five two-dimensional glass micromodels with different pore geometries were designed to assess the impact of pore geometries on the ultrasonic removal of asphaltene deposition.
View Article and Find Full Text PDFHot solvent-assisted gravity drainage (HS-AGD) is an effective way to exploit oil sands and heavy oil both economically and environmentally. The visualized microscopic seepage experiments and two-dimensional (2-D) macroscopic simulation experiments of HS-AGD are carried out, and the results are compared with that of steam-assisted gravity drainage (SAGD) in detail for the first time in order to compare their development effects of the oil sand reservoir. MacKay River oil sand bitumen is taken as an oil sample in the experiments, with -hexane as the solvent.
View Article and Find Full Text PDFJ Chromatogr A
January 2020
Université de Lyon, Institut des Sciences Analytiques, UMR 5280, CNRS, 5 rue de la Doua, 69100 Villeurbanne, France. Electronic address:
The petroleum industry is increasingly concerned with the conversion of vacuum residues as a consequence of decreased conventional crude oil availability. The compositional analysis of heavy oil products has become a key step in conversion processes, but the complexity of these oil matrices tends to increase with their boiling point. In this study, comprehensive two-dimensional liquid chromatography (LCxLC) coupled to inductively coupled mass spectrometry (ICP-MS/MS) is considered with a view to meet new requirements and to bring additional information regarding the species present in these matrices.
View Article and Find Full Text PDFJ Environ Manage
September 2019
Environmental Science and Engineering Department, IIT Bombay, Powai, Mumbai, 400 076, India. Electronic address:
Aged oily sludge was subjected to long term (90 day) slurry phase treatment (10% w/v oily sludge) using various biodegradation strategies involving intermittent spiking with nutrients (N), surfactant (S) and microorganisms (M), employed singly or in combination. The strategy involving simultaneous addition of N, S, and M (BNMS) resulted in the highest rate (0.0126 day) and extent of oil degradation (68.
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