Static and dynamic tensiometries show that a newly prepared water/asphaltenated cyclohexane interface behaves as expected: the mean area occupied per asphaltene molecule is 2 nm2, and variations of interfacial tension and dilatational elastic modulus with time indicate that equilibrium is reached more slowly than that for usual surfactants. The use of the time/temperature superposition principle allows a detailed rheological study of a 2 day old interface of the same type which has reached equilibrium. It is found that the two-dimensional asphaltene network exhibits a glass transition zone, behaves as a gel near its gelation point, and is built by a universal process of aggregation.

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http://dx.doi.org/10.1021/la049017bDOI Listing

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