Stereoselective synthesis of (+)-boronolide and its 8-epimer.

Org Biomol Chem

State Key Laboratory of Bio-organic & Natural Products Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai, 200032, China.

Published: August 2004

Starting from readily available carbohydrates the synthesis of 8-epi-(+)-boronolide 19 and (+)-boronolide was achieved with diastereoselective propargylation of alpha-oxygenated aldehyde as a key step.

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Source
http://dx.doi.org/10.1039/B406397JDOI Listing

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