Horse-spleen ferritin is known to crystallize in three different space groups, cubic F432, orthorhombic P2(1)2(1)2 and tetragonal P42(1)2, but only the cubic form has been fully investigated. Crystals of the tetragonal form of apoferritin have been obtained, by the vapour-diffusion technique, which diffract beyond 3.0 A. The unit-cell dimensions are a = b = 146.63, c = 152.94 A. The orientation of the non-crystallographic symmetry axes of the apoferritin molecule (24 subunits of 174 amino acids each, arranged in a 432 point symmetry rhombododecahedron) has been determined by a self-rotation Patterson function. The asymmetric unit is made of six subunits and was positioned by molecular replacement.
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http://dx.doi.org/10.1107/S0907444995016842 | DOI Listing |
Dalton Trans
January 2025
Czech Academy of Sciences, J. Heyrovsky Institute of Physical Chemistry, Dolejškova 2155/3, 182 23 Prague 8, Czech Republic.
Copper isotopes and their complexes are intensively studied due to their high potential for applications in radiodiagnosis and radiotherapy. Here, we study the Cu complex of 1,8-bis(2-hydroxybenzyl)-cyclam (HL), which forms an unexpected variety of isomers differing in the mutual orientation of the substituents on the cyclam nitrogen atoms, the protonation of the phenolate pendant, and the ligand denticity. The interconversion of the isomers is rather slow, which made the isolation, identification and investigation of some of the individual species possible.
View Article and Find Full Text PDFAnimals (Basel)
January 2025
Department of Chemistry and Biochemistry, Florida International University, Miami, FL 33199, USA.
Two convex polyhedra that markedly resemble the head of the flatback sea turtle hatchling are identified. The first example is a zygomorphic tetragonal dodecahedron, while the other, an even better matching structure, is a related tetradecahedron, herein speculated to arise from this particular dodecahedron via known mechanisms gleaned from studies of the behavior of foams. A segmented, biomorphic, convex polyhedral model to address cephalic topology is thus presented stemming from solid geometry, anatomical observations, and a recently computed densest local packing arrangement of fifteen slightly oblate spheroids in which fourteen oblate spheroids surround a central such spheroid.
View Article and Find Full Text PDFACS Nano
January 2025
Functional Materials Research Laboratory, School of Materials Science and Engineering, Tongji University, Shanghai 201804, P. R. China.
Polar vortices are predominantly observed within the confined ferroelectric films and the ferroelectric/paraelectric superlattices. This raises the intriguing question of whether polar vortices can form within relaxor ferroelectric ceramics and subsequently contribute to their energy storage performances. Here, we incorporate 10 mol % CaSnO into the 0.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
School of Optoelectronic Science and Engineering, University of Electronic Science and Technology of China (UESTC), Chengdu 610054, PR China.
Low-dimensional hybrid organic-inorganic perovskites (HOIPs) containing chiral organic ligands have recently emerged as promising candidates for circularly polarized light (CPL) detection, which can distinguish left- and right-handed CPL directly. However, the increase in responsivity and realization of self-powered CPL photodetector remain a challenge. Meanwhile, there is a trade-off between the photocurrent responsivity and the ability to differentially absorb CPL in detectors based on these low-dimensional perovskites.
View Article and Find Full Text PDFNanoscale
January 2025
Quantum Solid-State Physics, Department of Physics and Astronomy, KU Leuven, Belgium.
The photoelectrochemical (PEC) water splitting reaction of bimetallic AuCu ( = 1, 0.75, 0.5, 0.
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