A tungsten neopentylidene complex has been found to decompose to yield a heterochiral dimer that contains a W=W double bond and no bridging ligands. Decompositions of related bisalkoxide complexes also yield compounds that contain an "unsupported" W=W double bond, while a sample of [Mo(NAr)(CH2-t-Bu)(OC6F5)]2 has been found to be a homochiral species related to [W(NAr)(CH2-t-Bu)(OC6F5)]2.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1021/ja0400988 | DOI Listing |
Publication Analysis
Top Keywords
w=w double
8
double bond
8
formation dimers
4
dimers unbridged
4
unbridged wiv/wiv
4
wiv/wiv double
4
double bonds
4
bonds tungsten
4
tungsten neopentylidene
4
neopentylidene complex
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!