We investigate the odd and even character of the shielding response in a chiral molecule (modeled by a Ne8 helix) when subjected to a chiral potential. We establish that the diastereomeric splittings are a measure of odd powers of Vodd. Implications for diastereomeric, splittings of Xe in handed cages with handed tethers are discussed.

Download full-text PDF

Source
http://dx.doi.org/10.1063/1.1641012DOI Listing

Publication Analysis

Top Keywords

odd character
8
character shielding
8
shielding response
8
response chiral
8
chiral potential
8
diastereomeric splittings
8
nuclear magnetic
4
magnetic shielding
4
shielding chirality
4
chirality odd
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!