Vibrational branching ratios in photoionization of CO and N2.

J Chem Phys

Department of Chemistry, Louisiana State University, Baton Rouge, Louisiana 70803, USA.

Published: January 2004

We report results of experimental and theoretical studies of the vibrational branching ratios for CO 4sigma(-1) photoionization from 20 to 185 eV. Comparison with results for the 2sigma(u)(-1) channel of the isoelectronic N2 molecule shows the branching ratios for these two systems to be qualitatively different due to the underlying scattering dynamics: CO has a shape resonance at low energy but lacks a Cooper minimum at higher energies whereas the situation is reversed for N2.

Download full-text PDF

Source
http://dx.doi.org/10.1063/1.1631818DOI Listing

Publication Analysis

Top Keywords

branching ratios
12
vibrational branching
8
ratios photoionization
4
photoionization report
4
report experimental
4
experimental theoretical
4
theoretical studies
4
studies vibrational
4
ratios 4sigma-1
4
4sigma-1 photoionization
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!