The title compound, BINAP oxide, C(44)H(32)O(2)P(2), (I), was synthesized by direct oxidation of (R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl (BINAP) with tert-butyl hydroperoxide in toluene solution. The angle between the naphthyl planes of the binaphthyl group is 94.17 (3) degrees.
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| http://dx.doi.org/10.1107/S0108270100006508 | DOI Listing |
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