The conditions for identification and quantilication of Pb(II) and Cd(II) ions as impurities in homeopathic preparations by stripping voltammetry were established. The tests proved that the method was of high selectivity. The detection limits were 0.78 ng/mL and 1.56 ng/mL for Pb(II) and Cd(II) ions, respectively. The method was characterised by: repeatability of measurements, a wide range of linearity and satisfactory percent recovery. The Pb(II) and Cd(II) ions were detected in examined drugs as impurities at concentrations of 1.23 ? 9.5 ng/mL and 1.66 ? 3.7 ng/mL for Pb(II) and Cd(II), accordingly.
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Int J Biol Macromol
January 2025
Department of Chemistry, Faculty of Science, Arak University, Arak 38481-77584, Iran; Institute of Nanosciences &Nanotechnology, Arak University, Arak, Iran. Electronic address:
The rapid industrialization and human activities in catchments have posed notable global challenges in removing of heavy metal contaminants from wastewater. Here, Schiff-bases (SB) of cyanoguanidine (CG) and salicylaldehyde (SA) were covalently grafted on a magnetic nanocomposite of chitosan to form a hybrid magnetic nanostructure (FeO@CS-CGSB). The synthesized structure was characterized using various techniques such as Fourier transform infrared spectroscopy (FT-IR), field emission scanning electron microscopy (SEM), transmission electron microscopy (TEM), powder X-ray diffraction (XRD), thermogravimetric analysis (TGA), vibrating sample magnetometry (VSM), dynamic light scattering (DLS), zeta potential, and Brunauer-Emmett-Teller surface area analysis (BET).
View Article and Find Full Text PDFJ Hazard Mater
January 2025
School of Civil Engineering, Hunan University of Science and Technology, Xiangtan, Hunan 411201, China.
A carbon-magnetic modified sepiolite nanocomposite (γ-FeO/SiO-Mg(OH)@BC) was synthesized using a hydrothermal method, consisting of γ-FeO, activated sludge biochar (BC), and alkali-modified sepiolite. Its ability to remove heavy metals such as Sb(V), Pb(II), Cd(II), and Zn(II) was investigated through adsorption experiments. Using response surface optimization, the optimal adsorption conditions were determined: adsorption time = 3.
View Article and Find Full Text PDFAnal Chem
January 2025
Laboratory of Analytical Chemistry, Department of Chemistry, University of Athens, Athens 157 71, Greece.
This work describes fully integrated multifolding electrochemical paper-based devices (ePADs) for enhanced multiplexed voltammetric determination of heavy metals (Zn(II), Cd(II), and Pb(II)) using tunable passive preconcentration. The paper devices integrate five circular sample preconcentration layers and a 3-electrode electrochemical cell. The hydrophobic barriers of the devices are drawn by pen-plotting with hydrophobic ink, while the electrodes are deposited by screen-printing.
View Article and Find Full Text PDFWorld J Microbiol Biotechnol
December 2024
Department of Bioengineering and Biotechnology, Huaqiao University, Xiamen, 361021, China.
Heavy metal and nitrogen contaminations are serious concerns in aquatic environments. Marichromatium gracile YL28, a marine purple sulfur bacterium, has shown great potential as a bioremediation agent for removing inorganic nitrogen from marine water. This study further investigated its ability to simultaneously absorb heavy metals, including Pb(II), Cu(II), Cd(II) and Cr(VI), and remove inorganic nitrogen.
View Article and Find Full Text PDFBull Environ Contam Toxicol
December 2024
Department of Chemistry, Faculty of Science, Ondokuz Mayıs University, Kurupelit, Samsun, 55139, Türkiye.
Fast-paced global industrialization due to population growth poses negative water implications, such as pollution by heavy metals. Phytoremediation is deemed as an efficient and environmentally friendly alternative which utilizes different types of hyperaccumulator plants known as macrophytes for the removal of heavy metal pollutants from contaminated water. In this study, the removal of Cu(II), Ni(II), Pb(II), and Cd(II) heavy metal ions contaminated water was studied by using an aquatic plant, Persicaria amphibia (L.
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