This paper reports a simple way to synthesize an allenylidene rhenium(VII) complex. The diimido adamantyl-thiolato allenylidene rhenium(VII) complex 2 was obtained through a metathetical reaction of phosphonioalkylidyne rhenium complex 1 with diphenylketene and also structurally analyzed with X-ray diffraction. Complex 2 is the first d0 allenylidene complex with structure information.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1021/ja048030f | DOI Listing |
Publication Analysis
Top Keywords
allenylidene rheniumvii
8
rheniumvii complex
8
complex
6
simple synthesis
4
allenylidene
4
synthesis allenylidene
4
allenylidene heptavalent
4
heptavalent rheniumd0
4
rheniumd0 complex
4
complex paper
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!