AI Article Synopsis
- - The compound (Me(3)Si)(3)SiK[middle dot]18-crown-6 reacts with SbCl(3) in a 3:1 ratio to produce the complex [(Me(3)Si)(3)SiSb](4)! - Potassium in the reaction serves first as a nucleophile, attacking the antimony, and then as a coupling agent that facilitates the formation of Sb-Sb bonds! - This process demonstrates a straightforward method for synthesizing the title complex by leveraging the chemistry of silicon and antimony compounds!
Article Abstract
The reaction of (Me(3)Si)(3)SiK[middle dot]18-crown-6 with SbCl(3)(3 : 1 equiv.) provides a simple route to the title complex [(Me(3)Si)(3)SiSb](4). The potassium base initially acts as a nucleophile and then as a coupling agent, forming Sb-Sb bonds.
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| http://dx.doi.org/10.1039/B405032K | DOI Listing |
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