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New synthesis of 1,4-diketones via rhodium-catalysed 1,4 carbonylative addition of arylboronic acids to alpha,beta-unsaturated ketones. | LitMetric
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New synthesis of 1,4-diketones via rhodium-catalysed 1,4 carbonylative addition of arylboronic acids to alpha,beta-unsaturated ketones.

Mathieu Sauthier Yves Castanet André Mortreux

Chem Commun (Camb)

Laboratoire de Catalyse de Lille, UMR CNRS 8010, ENSCL, BP 108, 59652 Villeneuve d'Ascq, France.

Published: July 2004

The reaction of various arylboronic acids with alpha,beta-unsaturated ketones under CO pressure and in the presence of rhodium catalyst yields 1,4-diketones.

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 Source
http://dx.doi.org/10.1039/b403415eDOI Listing

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