Experimental study of water-ice catalyzed thermal isomerization of cyanamide into carbodiimide: implication for prebiotic chemistry.

J Am Chem Soc

Physique des Interactions Ioniques et Moléculaires, UMR 6633, Université de Provence et CNRS, Centre de St. Jérôme, case 252, 13397 Marseille Cedex 20, France.

Published: June 2004

AI Article Synopsis

  • Cyanamide (NH2CN) is significant in prebiotic chemistry and is of interest in interstellar studies.
  • Research demonstrates that cyanamide can be converted to carbodiimide (HNCNH) using a water-ice surface as a catalyst through isomerization.
  • This conversion happens at low temperatures (below 100 K), which aligns with conditions found in interstellar clouds made up predominantly of water ice.

Article Abstract

Cyanamide (NH2CN) is a molecule of interstellar interest which can be implied in prebiotic chemistry. We showed, by FTIR spectroscopy, that cyanamide can be isomerized in carbodiimide (HNCNH), another interstellar relevant molecule, by a reaction involving the amorphous water-ice surface as catalyst. This isomerization occurs at low temperature (T < 100 K) which agrees quite well with that expected in the interstellar clouds composed of dust grains in which water is the most predominant constituent.

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Source
http://dx.doi.org/10.1021/ja048721bDOI Listing

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