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Interesting behavior of alpha,beta-unsaturated oximes in intramolecular [4 + 2] cycloaddition reactions. | LitMetric

Interesting behavior of alpha,beta-unsaturated oximes in intramolecular [4 + 2] cycloaddition reactions.

Org Lett

Johnson & Johnson Pharmaceutical Research and Development, LLC, 1000 Route 202, Box 300, Raritan, New Jersey 08869, USA.

Published: June 2004

[structure: see text] Intramolecular [4 + 2] cycloaddition using alpha,beta-unsaturated oximes was explored. The reactions proceeded under unusually facile conditions to furnish the nitrones. The latter were subsequently reacted with DMAD to afford [3 + 2] cycloaddition products.

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Source
http://dx.doi.org/10.1021/ol049640nDOI Listing

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