The diffusive motion of the conducting electrons in the one-dimensional organic conductor FA2PF6 (FA, Fluoranthene) is studied with the ESR pulse-gradient spin-echo (PGSE) signal combined with spatial density ESR imaging. A local measurement of the short restricted regions reveals diffraction patterns in the local PGSE data. A model calculation adapted to the local measurements provides a highly accurate quantitative description of the results. The appearance of these patterns provides information about the diffusive motion of the charge at the crystal boundaries.
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http://dx.doi.org/10.1103/PhysRevLett.92.156803 | DOI Listing |
Chemphyschem
August 2017
Universität Tübingen, Institut für Organische Chemie, Auf der Morgenstelle 18, 72076, Tübingen, Germany.
6,13-Bis[tri(isopropyl)silylethynyl]pentacene is a prototypical molecule for organic semiconductor and photovoltaic materials, which makes its electrochemical (redox) properties highly interesting. However, previous cyclic voltammetric studies have provided only limited information. Kinetic and persistence information and identification of the oxidation product(s) and their further reaction or oxidation have not been reported.
View Article and Find Full Text PDFPhys Rev Lett
April 2004
Racah Institute, Hebrew University, Jerusalem, Israel.
The diffusive motion of the conducting electrons in the one-dimensional organic conductor FA2PF6 (FA, Fluoranthene) is studied with the ESR pulse-gradient spin-echo (PGSE) signal combined with spatial density ESR imaging. A local measurement of the short restricted regions reveals diffraction patterns in the local PGSE data. A model calculation adapted to the local measurements provides a highly accurate quantitative description of the results.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!