Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/b403616f | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Phosphate-Buffered Saline and Dimethyl Sulfoxide Enhance the Antivenom Action of Ruthenium Chloride against Venom in Human Plasma-A Preliminary Report.
Int J Mol Sci
June 2024
Department of Anesthesiology, The University of Arizona College of Medicine, Tucson, AZ 85724, USA.
Ruthenium chloride (RuCl) is widely utilized for synthesis and catalysis of numerous compounds in academia and industry and is utilized as a key molecule in a variety of compounds with medical applications. Interestingly, RuCl has been demonstrated to modulate human plasmatic coagulation and serves as a constituent of a compounded inorganic antivenom that neutralizes the coagulopathic effects of snake venom in vitro and in vivo. Using thrombelastography, this investigation sought to determine if RuCl inhibition of the fibrinogenolytic effects of venom could be modulated by vehicle composition in human plasma.
View Article and Find Full Text PDFIn Situ Structural Determination of a Homogeneous Ruthenium Racemization Catalyst and Its Activated Intermediates Using X-Ray Absorption Spectroscopy.
Chemistry
March 2020
Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, 10691, Stockholm, Sweden.
The activation process of a known Ru-catalyst, dicarbonyl(pentaphenylcyclopentadienyl)ruthenium chloride, has been studied in detail using time resolved in situ X-ray absorption spectroscopy. The data provide bond lengths of the species involved in the process as well as information about bond formation and bond breaking. On addition of potassium tert-butoxide, the catalyst is activated and an alkoxide complex is formed.
View Article and Find Full Text PDFOne-Pot Seed-Mediated Growth of Co Nanoparticles by the Polyol Process: Unraveling the Heterogeneous Nucleation.
Nano Lett
December 2019
Université de Toulouse, UMR 5215 INSA, CNRS, UPS, Laboratoire de Physique et Chimie des Nano-Objets , 135 Avenue de Rangueil , F-31077 Cedex 4 Toulouse , France.
Article Synopsis
- The one-step seed-mediated synthesis method is popular for creating ferromagnetic metal nanoparticles due to its ability to control particle shape, but it has limited mechanistic studies.
- This research focuses on the heteronucleation process during the synthesis of cobalt nanoparticles in liquid polyols, using high-resolution imaging and hydrogen evolution measurements to track nucleation and growth.
- The study reveals that iridium and ruthenium seeds play a crucial role in the nucleation, and their influence on cobalt's microstructure varies, showcasing the relationship between the nucleating agent and particle formation.
Ruthenium trichloride catalyzed conversion of cellulose into 5-hydroxymethylfurfural in biphasic system.
Bioresour Technol
May 2019
School of Chemistry, Biology and Materials Engineering, Suzhou University of Science and Technology, Suzhou 215009, PR China; College of Pharmaceutical Sciences, Soochow University, Suzhou 215123, PR China.
The production of 5-hydroxymethylfurfural (5-HMF) from cellulose catalyzed by a series of transition metal chlorides (i.e. FeCl, RuCl, VCl, TiCl, MoCl and CrCl) was studied in biphasic system.
View Article and Find Full Text PDFRuthenium Incorporated Cobalt Phosphide Nanocubes Derived From a Prussian Blue Analog for Enhanced Hydrogen Evolution.
Front Chem
October 2018
Department of Physics, Harbin Institute of Technology, Harbin, China.
Electrochemical water splitting in alkaline media plays an important role in mass production of hydrogen. Ruthenium (Ru), as the cheapest member of platinum-group metals, has attracted much attention, and the incorporation of trace amount of Ru with cobalt phosphide could significantly improve the hydrogen evolution reaction (HER) catalytic activity. In this work, ruthenium-incorporated cobalt phosphide nanocubes are synthesized via a reaction between Co-Co Prussian blue analog (Co-PBA) and ruthenium chloride (RuCl) followed by the phosphidation.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!