AI Article Synopsis
- - The study investigates how double asymmetric induction acts as a tool to understand the mechanism behind a specific chemical reaction.
- - It focuses on the conjugate addition of two different types of lithium amides to a particular compound, revealing that the key reactive form of the compound is the anti-s-cis conformation.
- - This conformation enhances the production of a pseudotripeptide, showcasing the significance of molecular orientation in asymmetric synthesis.
Article Abstract
Double asymmetric induction as a mechanistic probe indicates that, for the conjugate addition of (R)- and (S)-lithium N-benzyl-N--alpha-methylbenzylamide to (S)-3'-phenylprop-2'-enoyl-4-benzyloxazolidinone, the reactive conformation of the N-acyl oxazolidinone is the anti-s-cis form, facilitating the asymmetric synthesis of a pseudotripeptide.
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| http://dx.doi.org/10.1039/b401293c | DOI Listing |
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