Porphyrin ring contraction: a one-pot reaction leading to divalent corroles.

Chem Commun (Camb)

Universite Louis Pasteur, UMR CNRS 7123, Faculte de Chimie, 1 rue Blaise Pascal, 67000 Strasbourg, France.

Published: May 2004

Reaction of nickel meso-tetraarylporphyrins with benzoic anhydride and tin tetrachloride, followed by air oxidation under basic conditions, results in ring contraction, yielding divalent corroles.

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Source
http://dx.doi.org/10.1039/b400812jDOI Listing

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