Previous observations of the nontransient oscillations of rising bubbles and falling spheres in wormlike micellar fluids were limited to a single surfactant system. We present an extensive survey of rising bubbles in another system, an aqueous solution of cetylpyridinium chloride and sodium salicylate, with and without NaCl, across a range of concentrations and temperatures. Two different types of oscillations are seen in different concentration ranges, each with its own temperature dependence. Rheological data identify these different hydrodynamic states with different fluid microstructures.
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http://dx.doi.org/10.1103/PhysRevLett.92.124501 | DOI Listing |
Molecules
November 2024
School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, China.
Wormlike micelles (WLMs) with tunable viscoelastic characteristics have emerged as indispensable smart materials with a wide range of applications, which have garnered intense interest over the past few decades. However, quantitatively predicting the effect of various hydrotropes on the rheological behaviors of WLMs remains a challenge. In this article, micelles were formed in a mixture of 3-hexadecyloxy-2-hydroxypropyltrimethylammonium bromide (RHTAB) and aromatic hydrotropes (e.
View Article and Find Full Text PDFLangmuir
September 2024
The Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi, Jiangsu 214122, China.
Herein, a quaternary ammonium surfactant with dual heads and tails, ,,,,-pentamethyl--(3-(2-tetradecylhexadecanamido)propyl)propane-1,3-diaminium dibromide, abbreviated as Di-C14-N2, was synthesized. For the first time, clear observation of aggregate structures formed by surfactants in pure glycerol systems was achieved using cryogenic transmission electron microscopy (cryo-TEM). The system's rheological properties were analyzed using both steady-state shear and oscillatory rheological measurements.
View Article and Find Full Text PDFSoft Matter
September 2024
Micro/Bio/Nanofluidics Unit, Okinawa Institute of Science and Technology Graduate University, Onna-son, Kunigami-gun, Okinawa 904-0495, Japan.
We present a comprehensive investigation combining numerical simulations with experimental validation, focusing on the creeping flow behavior of a shear-banding, viscoelastic wormlike micellar (WLM) solution over concavities with various depths () and lengths (). The fluid is modeled using the diffusive Giesekus model, with model parameters set to quantitatively describe the shear rheology of a 100 : 60 mM cetylpyridinium chloride:sodium salicylate aqueous WLM solution used for the experimental validation. We observe a transition from "cavity flow" to "expansion-contraction flow" as the length exceeds the sum of depth and channel width .
View Article and Find Full Text PDFJ Colloid Interface Sci
October 2024
Physics Department, Moscow State University, 119991 Moscow, Russia.
Hypothesis: The formation of micellar aggregates and the changes in their morphology are crucial for numerous practical applications of surfactants. However, a proper structural characterization of complicated micellar nanostructures remains a challenge. This paper demonstrates the advances of cryo-electron tomography (cryo-ET) in revealing the structural characteristics that accompany the evolution of surfactant aggregates.
View Article and Find Full Text PDFSoft Matter
June 2024
Department of Mechanical Engineering, University of British Columbia, 6250 Applied Science Ln, Vancouver, British Columbia V6T1Z4, Canada.
Wormlike micellar solutions formed by long-chained zwitterionic surfactants show gel-like rheology at room temperature and have recently been found to exhibit other complex and interesting rheological features. We study the dynamics of these wormlike micellar gels in a pipe-flow scenario using particle imaging and tracking velocimetry and report the existence of plug flows with strong wall slip and non-parabolic velocity profiles for different surfactant concentrations and imposed flow rates. We rationalize these results as features of a developing transient flow of a viscoelastic solution in space and time.
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