The title compound, [Nd(C(10)H(16)O(4))(C(10)H(17)O(4))(H(2)O)](n), has a novel Nd-organic framework constructed from sebacic acid (C(10)H(18)O(4)) linkers, the longest aliphatic ligand used to date in lanthanide metal-organic framework compounds. The structure contains edge-shared chains of NdO(8)(H(2)O) tricapped trigonal prisms that propagate in the [100] direction, with Nd-O distances in the range 2.414 (4)-2.643 (4) A.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1107/S0108270104003427 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Poly[bis[aquaneodymium(III)]-mu2-oxalato-di-mu4-succinato].
Acta Crystallogr C
November 2007
School of Materials and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, People's Republic of China.
In the title compound, [Nd(2)(C(4)H(4)O(4))(2)(C(2)O(4))(H(2)O)(2)](n), the flexible succinate anion assumes the gauche conformation and bridges the nine-coordinate Nd atoms to generate two-dimensional layers parallel to (010). The coordination polymer layers are linked into a three-dimensional framework by the rigid oxalate ligands. The oxalate ions are located on a center of inversion.
View Article and Find Full Text PDFPoly[[aquaneodymium(III)]-micro(3)-decane-1,10-dicarboxylato-micro(3)-9-carboxynonanecarboxylato].
Acta Crystallogr C
April 2004
Department of Chemistry, George Washington University, 725 21st Street NW, Washington, DC 20052, USA.
The title compound, [Nd(C(10)H(16)O(4))(C(10)H(17)O(4))(H(2)O)](n), has a novel Nd-organic framework constructed from sebacic acid (C(10)H(18)O(4)) linkers, the longest aliphatic ligand used to date in lanthanide metal-organic framework compounds. The structure contains edge-shared chains of NdO(8)(H(2)O) tricapped trigonal prisms that propagate in the [100] direction, with Nd-O distances in the range 2.414 (4)-2.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!